Those (Properties.Settings.Default) are usersettings, placed in the "Documents and Settings\[user]\Local Settings\Application Data\[app_name]\[assembly_version]\"-folder. If that's what you want, it's correct. The Reload() method is not necessary since you just saved them anyway. This method could be useful when you update a setting - e.g. Upload -, and don't save it, when you do a reload without the saving you'll get (back) the original value for the properties. When reloading after running the save() method, you basically just load what you just saved - and what is already in the property-values - so it's useless.
Actually, why do you ask it You get any errors / exceptions
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