If you have mapped the network drive as F: first then won't allow you to map the USB unless there is a free drive letter to assign logical usb/drives from A: - F:.
What logical mappings do you have, a : floppy C&D HDD partition E: or F: as cd drives
Have you checked in device manager to see if the USB ports are working OK and stuff
As a rule i would start network drives from H: and above. Again depends if your drive letters are assign over a logon script, etc Is your machine part of a domain
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